Classical and Molecular Thermodynamics of Fluid Systems - Vera, Juan H.; Wilczek-Vera, Grazyna; Olivera-Fuentes, Claudio; - Prospero Internetes Könyváruház
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Classical and Molecular Thermodynamics of Fluid Systems

Principles and Applications
 
Kiadás sorszáma: 2
Kiadó: CRC Press
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Rövid leírás:

This text explores the connections between different thermodynamic subjects related to fluid systems, from first principles to applied topics. It presents the fundamentals and treatment of mixtures and offers examples and references. The new edition explores advances and contains problems and solutions.

Hosszú leírás:

This text explores the connections between different thermodynamic subjects related to fluid systems. In an innovative way, it covers the subject from first principles to the state of the art in fundamental and applied topics. Using simple nomenclature and algebra, it clarifies concepts by returning to the conceptual foundation of thermodynamics. The structural elements of classical and molecular thermodynamics of fluid systems presented cover, via examples and references, both the usefulness and the limitations of thermodynamics for the treatment of practical problems. This new edition explores recent advances in statistical associated fluid theories and contains creative end?of?chapter problems connecting the theory with real?life situations. It includes new chapters on thermodynamics of polymer solutions and molecular thermodynamics and also presents advances in the study of the activity of individual ions.



  • Provides a concise structure of concepts, using simple nomenclature and algebra

  • Clarifies problems usually overlooked by standard texts

  • Features end?of?chapter problems to enhance the reader?s understanding of the concepts

  • Includes diverse topics of interest to researchers and advanced students, including elements of statistical thermodynamics, models of solutions, statistical associated fluid theory and the activity of individual ions

  • Offers four appendices giving step?by?step procedures and parameters for direct use of the PRSV equation of state and the ASOG?KT group method for fugacity and activity coefficient calculations

  • Features a complete set of solutions to problems throughout the book, available for download on the book?s webpage under "Support Material"

This textbook is written for advanced undergraduate and graduate students studying chemical engineering and chemistry as well as for practicing engineers and researchers.

Tartalomjegyzék:

Section I: Fundamentals. 1. Basic Concepts and Definitions. 2. The First and Second Laws of Thermodynamics. 3. Conservation of Energy in an Open Flow System: Definition of Enthalpy. 4. The Algebra of State Functions: The Helmholtz and Gibbs Functions. 5. Calculation of Changes in the Value of Thermodynamic Properties. Section II: Mixtures. 6. Partial Molar Properties and Property Changes by Mixing. 7. The Chemical Potential and the Gibbs?Helmholtz Equation. 8. The Principles of Physical and Chemical Equilibrium. 9. The Phase Rule and Duhem?s Theorem. 10. Generality of the Thermodynamic Treatment for More Complex Systems. 11. Ideal Gas and Ideal Gas Mixtures. 12. Equilibrium in Terms of Fugacity and Activity. 13. Calculation of Fugacities from Equations of State. 14. Fugacity of a Mixture and of Its Components. 15. Fugacities, Activities, and Activity Coefficients in Liquid Mixtures of Nonelectrolytes. 16. Activity Coefficients and Excess Properties. 17. Mixture Behavior, Stability, and Azeotropy. 18. The Thermodynamics of Aqueous Electrolyte Solutions. 19. The Thermodynamics of Polymer Solutions. Section III: Applications. 20. Applications of Polymer Solution Thermodynamics. 21. The Thermodynamics of Chemical Reactions. 22. The Thermodynamics of Equilibrium?Based Separation Processes. 23. Heat Effects. 24. Adsorption of Gases on Solids. Section IV: Special Topics. 25. Thermodynamics of Flow of Compressible Fluids. 26. Elements of Statistical Thermodynamics. 27. Statistical Thermodynamics Basis of Equations of State. 28. Statistical Thermodynamics Justification of Some Commonly Used Expressions for the Excess Gibbs Energy. 29. Statistical Thermodynamics Approach to the Generalized van der Waals Theory: Toward Understanding of the Molecular Behavior of Fluids. 30. Generalized Lattice?Fluid Model. 31. COSMO?RS?Type Models. 32. Thermodynamics of Hydrogen Bonding. 33. The Family of SAFT Equation?of?State Models. 34. The Activity of Individual Ions?Past, Present and Future: In Memory of Dr. Dan Fraenkel, April 1, 1946?March 8, 2023. Section V: Appendices. Section VI: Solutions to End-of-Chapter Problems.